J. Groos, M. Koy, J. Musso, M. Neuwirt, T. Pham, P. M. Hauser, W. Frey, and M. R. Buchmeiser Organometallics 2022, 41, 10, 1167–1183.
Poly(urethane)-based polymeric monolithic materials with mesopores, e.g., 5, 10, 15 or 20±1 nm in diameter, will be generated. Janus-type nanoparticles equipped with one polymer-compatible and one polymer-incompatible hemisphere will be used in course of monolith synthesis such that they are finally located and half-embedded at the surface of the structure forming microglobules. Alternatively, polymeric monoliths with a defined pore-size distribution will be generated via solvent-induced phase separation. Pore-size selective functionalization approaches are outlined.
- Can we introduce tailored mesoporosity in the range of 2–20 nm into polymeric monoliths, whether by a hard templating or a solvent-induced phase separation approach?
- How narrow is the pores size distribution?
- How do surface-located functional groups influence catalyst activity, e.g. in olefin metathesis?
- Can polymeric mesoporous monoliths in combination with supported ionic liquid phase (SILP) technology provide a suitable confinement for catalytic reactions?
M. Pucino, W.‐C. Liao, K. W. Chan, E. Lam, R. Schowner, P. A. Zhizhko, M. R. Buchmeiser and C. Copéret Helv. Chim. Acta 2020, 103, e2000072.
M. Pucino, M. Inoue, C. P. Gordon, R. Schowner, L. Stöhr, S. Sen, C. Hegedüs, E. Robé, F. Tóth, M. R. Buchmeiser and C. Copéret Angew. Chem. Int. Ed. 2018, 57, 4566–14569. .