Collaborative Research Center 1333
Molecular Heterogeneous Catalysis
in Confined Geometries
Electrocatalysis under confinement: CO2-reduction with molecular catalysts immobilized on ordered mesoporous carbons
– New project since July 2022 –
Ordered mesoporous carbon (OMC) films with distinct pore sizes in the range of 3-18 nm and an adjusted wall polarity will be synthesized to design thin film electrodes (TFE) and gas diffusion electrodes (GDEs) for an optimized electrocatalytic reduction of CO2. The catalysts are selectively immobilized inside the mesopores via a silylation strategy. Confinement effects and the activity/selectivity of the electrocatalysts will be electrochemically characterized, and full cell measurements will be conducted to evaluate the stability and the scalability of the confinement effects. Relevant microscopic processes will be elucidated via simulations in order to set up an adequate continuum-based reaction-diffusion model for the full electrocatalytic cycle.
– REVIEW- F. Hauf, S. Van Daele, M. K. Birhanu, S. Haufe, T. Breugelmans, E. Klemm
Current Opinion in Chemical Engineering 2026, 51, 101222.
F. Hauf, R. Kollmuß, S. Haufe and E. Klemm
ChemistryOpen, 2026, 15, e202500611.
F. Hauf, R. Kollmuß, S. Haufe and E. Klemm
Adv. Sustainable Syst. 2025, 9, e00846.
S. Kolin, M. Marquardt, G. Fläschner, S. Naumann, K. Pluhackova
ACS Materials Lett. 2025, 7, 3714–3723.
– MINIREVIEW- M. Huber, P. Sonnenberg, S. Naumann
Polym. Chem. 2025, 16, 1627-1646.
P. Vogel, D. Beyer, Ch. Holm and T. Palberg
Soft Matter 2024, 20, 9261-9272.
M. Marshall, Z. Dilruba, A.-K. Beurer, K. Bieck, S. Emmerling, F. Markus, Ch. Vogler, F. Ziegler, M. Fuhrer, S. S. Y. Liu, S. R.Kousik, W. Frey, Y. Traa, J. R. Bruckner, B. Plietker, M. R. Buchmeiser, S. Ludwigs, S. Naumann, P. Atanasova, B. V. Lotsch, A. Zens and S. Laschat
Eur. J. Org. Chem. 2024, 27, e202400283.
O. Bunjaku, J. Florenski, J. Wischnat, E. Klemm, O. V. Safonova, J. van Slageren, and D. P. Estes
Inorg. Chem. 2024, 63, 16, 7512–7519.
I. Haug, J. Reitz, C. Ziane, M. R. Buchmeiser, M. M. Hansmann and S. Naumann
Macromol. Rapid Commun. 2024, 2300716.
A. S. Hazari, S. Chandra, P. M. Becker, H. Liu, E. Klemm, J. Kästner, B. Sarkar
ChemRxiv 2024.
I. Tischler, A. Schlaich and Ch. Holm
ACS Omega2024, 9, 1, 598–606.
J. Yang, S. Kondrat, Ch. Lian, H. Liu, A. Schlaich and Ch. Holm
Phys. Rev. Lett. 2023, 131, 118201.
H. Jäger, A. Schlaich, J. Yang, Ch. Lian, S. Kondrat and Ch. Holm
Faraday Discuss., 2023, 246, 520-539.
M. Kirchhof, K. Gugeler, A.-K. Beurer, F. R. Fischer, D. Batman, S. M. Bauch, S. Kolin, E. Nicholas, R. Schoch, Ch. Vogler, S. R. Kousik, A. Zens, B. Plietker, P. Atanasova, S. Naumann, M. Bauer, J. R. Bruckner, Y. Traa, J. Kästner and Sabine Laschat
Catal. Sci. Technol., 2023, 13, 3709-3724.
E. Kersten, O. Linker, J. Blankenburg, M. Wagner, P. Walther, S. Naumann and H. Frey
Macromol. Chem. Phys. 2023, 2300097.
S. Chandra, A. S. Hazari, Q. Song, D. Hunger, N. I. Neuman, J. van Slageren, E. Klemm and B. Sarkar
ChemSusChem 2023, 16, e202201146.
M. R. Buchmeiser, D. Imbrich, D. Wang and S. Naumann
J. Organomet. Chem. 2023, 991, 122674.
F. Stein, M. Nößler, A. S. Hazari, L. Böser, R. Walter, H. Liu, E. Klemm and B. Sarkar
Chem.Eur.J. 2023, 29, e2023004.
Ch. Vogler, S. Naumann and J. R. Bruckner
Mol. Syst. Des. Eng., 2022, 7, 1318-1326.
© University Stuttgart 2026
You are currently viewing a placeholder content from hCaptcha. To access the actual content, click the button below. Please note that doing so will share data with third-party providers.
More InformationYou need to load content from reCAPTCHA to submit the form. Please note that doing so will share data with third-party providers.
More InformationYou are currently viewing a placeholder content from Turnstile. To access the actual content, click the button below. Please note that doing so will share data with third-party providers.
More Information
