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Collaborative Research Center 1333

Molecular Heterogeneous Catalysis in Confined Geometries

Collaborative Research Center 1333
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  • Research
    • Area A: Materials
      • A03 – Electrocatalytic CO2 Reduction with COFs
      • A04 – Mesoporous Metallo-Silicates
      • A08 – Dynamic Confinement in Soft Porous Crystals
    • Area B: Catalysis
      • B02 – Continuous Flow and On-line Analytics
      • B04 – Tuning C6/C8 Selectivity in Oligomerizations
      • B05 – Gas-Phase CO2 Reduction by Cu Hydrides
      • B06 – Cooperative Multiple Activation Catalysis
      • B07 – Electrocatalytic CO2 Reduction on Carbon
      • B08 – Probing Precatalyst Association by NMR
    • Area C: Analysis, Theory and Simulation
      • C02 – Porphyrinoids & Pyridyl Carbenes
      • C03 – Understanding Atom Probe Tomography
      • C04 – Simulation of Chemical Reactivities
      • C05 – Simulation of Diffusion-Reaction Processes
      • C08 – Diffraction Analysis of Complex Structures
      • C09 – Microscopic Analysis of Molecular Transport
      • C10 – Advanced Hard X-Ray Spectroscopy
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Archives: Publikationen

Olefin Metathesis under Spatial Confinement and Continuous Flow: Investigation of Isomeric Side Reactions with a Grubbs–Hoveyda Type Catalyst

A. Böth, T. Roider, F. Ziegler, X. Xie, M. R. Buchmeiser and U. Tallarek ChemCatChem 2023, 15, e202201268.

Stereoselective Ring-Opening Metathesis Polymerization
with Tungsten Sulfido Alkylidene N-Heterocyclic Carbene
Complexes

M. R. Buchmeiser, P. Probst, D. Wang, and P. M. Hauser Macromol. Chem. Phys. 2023, 224, 2200350.

Oxo-Bridged Zr dimers as well-defined models of oxygen vacancies on ZrO2

E. J. Wimmer, S. V. Klostermann, M. Ringenberg, J. Kästner and D. P. Estes Eur. J. Inorg. Chem. 2023, e202200709.

A Practical and Robust Zwitterionic Cooperative Lewis Acid/Acetate/Benzimidazolium Catalyst for Direct 1,4-Additions

A. C. Hans, P. M. Becker, J. Haußmann, S. Suhr, D. M. Wanner, V. Lederer, F. Willig, W. Frey, B. Sarkar, J. Kästner and R. Peters Angew. Chem. Int. Ed. 2023, 62, e202217519.

Effect of liquid confinement on regioselectivity in the hydrosilylation of alkynes with cationic Rh(i) N-heterocyclic carbene catalysts

Panyam P. K. R. and M. R. Buchmeiser Faraday Discuss., 2023, 244, 39-50.

Hydrosilylation of Alkynes Under Continuous Flow Using Polyurethane-Based Monolithic Supports with Tailored Mesoporosity

H. Acikalin, P. K. R. Panyam, A. W. Shaikh, D. Wang, S. R. Kousik, P. Atanasova and M. R. Buchmeiser Macromol. Chem. Phys. 2023, 224, 2200234.

Determination of accessibility and spatial distribution of chiral Rh diene complexes immobilized on SBA-15 via phosphine-based solid-state NMR probe molecules

C. Rieg, M. Kirchhof, K. Gugeler, A. Beurer, L. Stein, K. Dirnberger, W. Frey, J. Bruckner, Y. Traa, J. Kästner, S. Ludwigs, S. Laschat and M. Dyballa Catal. Sci. Technol., 2023,13, 410-425.

Molybdenum Alkylidyne Silyloxy N-Heterocyclic Carbene
Complexes – Highly Active Alkyne Metathesis Catalysts that
can be Handled in Air

J. V. Musso, V. Gramm, S. Stein, W. Frey and M. R. Buchmeiser Eur. J. Inorg. Chem. 2023, 26, e202200649.

Imaging the Permeability and Passivation Susceptibility of SiO2 Nanosphere-Based Mesoporous Supports for Molecular Heterogeneous Catalysis under Confinement

S. R. Kousik, F. Ziegler, D. Sipp, A. Rodríguez-Camargo, H. Solodenko, W. Gassner, G. Schmitz, B. V. Lotsch, M. R. Buchmeiser, K. Koynov and P. Atanasova ACS Appl. Nano Mater. 2022, 5, 10, 14733–14745.

Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes Confined in Mesoporous Silica: Tuning Transition States Towards Z-Selective Ring-Opening Cross-Metathesis

E. L. Goldstein, F. Ziegler, A.-K. Beurer, Y. Traa, J. R. Bruckner, M. R. Buchmeiser ChemCatChem 2022,14, e202201008.

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